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Suitable for plastic varieties: PP/PE
Pigment contents:15%-30%
Reference ratio: 100/1-3
Light fastness: 7 (grade)
Carrier: PP / PE
Level: General
Active ingredient content: according to customer requirements
Color: various colors
Brand: Xinyang
Carrier: PE ;
Application: plastic products ;
Melting:105℃ ;
Temperature resistance: 300℃
Application: film, pipe, sheet, injection
Pigment contents: customized
Masterbatch is an aggregate obtained by uniformly
loading a super-constant pigment into a resin.
Color masterbatch is a new type of coloring agent
for coloring materials, also known as Pigment Preparation. It consists of three
basic elements: pigment or dye, carrier and additive. It is an aggregate
obtained by uniformly loading a super-constant pigment or dye into a resin. It
can be called PigmentConcentration, so the tinting strength of masterbatch is
higher than the pigment itself.
Basic ingredients:
1. Pigment or dye
Pigments are further divided into organic pigments
and inorganic pigments.
Commonly used organic pigments are: phthalocyanine
red, phthalocyanine blue, phthalocyanine green, fast red, macromolecular red,
macromolecular yellow, permanent yellow, permanent violet, azo red and other
commonly used inorganic pigments: cadmium red , cadmium yellow, titanium
dioxide, carbon black, iron oxide red, iron oxide yellow, etc.
2. Carrier
It is the matrix of the masterbatch. The special
color masterbatch generally selects the carrier resin same as the resin of
making the plastics, since the compatibility between the two is the best, but
the fluidity of the carrier is also considered.
3. Dispersant
The pigment is uniformly dispersed and no longer
aggregates. The melting point of the dispersing agent should be lower than that
of the resin, have good compatibility with the resin, and have good affinity
with the pigment. The most commonly used dispersants are: polyethylene low
molecular waxes, stearates.
4. Additives
Such as flame retardant, brightening,
antibacterial, antistatic, anti-oxidation and other varieties, unless the
customer asks, in general, the color masterbatch does not contain the above
additives.
Dedicated color masterbatch: According to the
plastic type specified by the user, this masterbatch selects the carrier resin
same as the resin for making customer’s plastic. For example, PP color
masterbatch and ABS color masterbatch respectively use PP and ABS as carriers.
Universal color masterbatch: This masterbatch also
takes certain resin (normally low melting point PE), but this masterbatch can
be applied to the coloration of other resins than its carrier resin.
The universal color masterbatch is relatively
simple and convenient, but has many disadvantages. It is recommended that you
use the special color masterbatch.
Most formal color masterbatch companies in the
world generally do not produce universal color masterbatches.
There are many disadvantages to the universal
color masterbatch. In fact, the general purpose of the universal color
masterbatch is very narrow, and the technical indicators and economic benefits
are also poor. The specific performance is as follows:
1. Poor predictability of coloring effect
The color masterbatch is used for coloring, and
the pigment of the universal color masterbatch exhibits different colors in
different plastics, so the coloring effect is less predictable.
2. Affect other properties of plastic products
In particular, it affects the strength, and the
product is easily deformed and twisted, which is more obvious to engineering
plastics.
3. Higher cost
In order to be 'universal', the universal color
masterbatch often uses a higher heat-resistant grade of pigment, resulting in
waste.
The color masterbatch can have several of these
functions at the same time, if the customer requires.
Sometimes, although the customer does not ask for
it, the color masterbatch company will advise the user to add some additives
depending on the needs of the product, such as adding certain additives such as
brighteners to the color masterbatch. Of course, this will increase the cost of
the product.
Heat resistance
The heat resistance grade of the special color
masterbatch is generally compatible with the plastic used for the product, and
can be used with confidence at normal temperature. Only in the following cases
will cause different degrees of discoloration, first, the temperature is beyond
the normal range; Second, the downtime is too long.
Masterbatch coloring has the following advantages
over granulation coloring:
1. Coloring and product processing are completed
once, avoiding the heating process of granulation coloring on plastics, and is
beneficial to the quality of plastic products.
2. The production process of plastic products is
simplified.
3. Can save a lot of power
There is no product that does not fade, and
products that use color masterbatch may still fade, but the fade degree of
product is different for different grades, some are more obvious, and some are
hard to detect.
The use of the color masterbatch is very simple,
it is only necessary to mix with the resin particles according to the prescribed
ratio, and it can be mixed by hand.
Pay attention to the following issues during the
operation of the device:
1.1. The mixing chamber of the injection molding
machine or extruder generally has multiple temperature zones, and the
temperature near the feed dropping port should be slightly higher. This is to
make the color masterbatch melt quickly and mixing evenly as soon as possible
with the plastic resin after entering the mixing chamber, which is beneficial
to the color masterbatch in a well dispersed state in the product.
1.2. Appropriate application of back pressure to
the injection molding machine can improve the mixing effect of the screw and
facilitate the dispersion of the pigment. The side effect of applying the back
pressure is to slow down the injection speed.
1.3. Increasing the temperature of the die of the
extruder can increase the brightness of the product.
The basis for determining the use ratio of the
masterbatch is to obtain a satisfactory coloring effect. As long as the surface
of the product is uniform in color and there are no streaks and spots, it can
be recognized. The proportion of color masterbatch can be selected as follows:
1:100 Unless
the mixing of the equipment is very good, it is prone to uneven pigment
dispersion. It is generally not recommended for customers to use this ratio.
However, some customers are particularly eager to
use this proportion of color masterbatch due to price pressure. For the sake of
customers, they also produce such a low proportion of concentrated color
masterbatch, and the dispersibility of the pigment can generally meet the
requirements.
1:50 This is used for coloring general plastic
products, mostly for PE and PP color
masterbatch.
1:33--1:25 For PO products with higher coloring
requirements, lower coloring requirements or general ABS products
1:20 This
is used in advanced plastic products, including PO and ABS, which can be widely
used in injection molding, blow molding, spinning and other processes.
1:20 or more Generally used for coloring
high-grade cosmetic containers, mostly used in small injection molding machines
The weight of the color masterbatch itself should
be deducted when calculating the cost of coloring the masterbatch.
For example: When 2 kg of color masterbatch is
added to 100 kg of plastic resin, the total weight is already 102 kg. Assuming
the resin price is 1.5 usd/kg, the color masterbatch price is 3 usd/kg.
The cost of using a color masterbatch in 102 kg
plastic product is:
2 kg × (3usd / kg -1.5usd / kg) = 3 usd
The cost added to each 100 kg of plastic product
due to the use of color masterbatch is:
3 usd / 102 kg × 100 kg = 2.94usd
In most cases that is true. In some cases,
however, coloring with color masterbatch is more economical than coloring with
toner, because colorists can achieve higher color pigment coloring through a
combination of several lower-priced pigments.
Also consider the following two phenomena:
1. In many cases, the choice of pigments used by
plastics manufacturers in color matching is not the most economical, and
because of the lack of familiarity with pigments, it is very common to repeatedly
test the color and cause waste of manpower and materials. This problem does not
exist with the color masterbatch used.
2. The products colored with the masterbatch and
the products colored with the toner are completely different in grade, and the
selling price is also higher. The selling price is often higher than the cost
increased by using the color masterbatch, so the color masterebatch can create
"profit" instead. From this perspective, in some cases, coloring with
color masterbatch is more economical than coloring with toner.
Color masterbatch do not need to be dried under
normal conditions and can be used directly. However, except for ABS and NY
masterbatch, they should be dried according to conventional techniques.
Color masterbatch can be stored for a long time.
The pigment in the color masterbatch is dispersed
and fixed in the carrier resin, and is in a closed state, and the quality does
not change even if it is stored for a long period of time. But should be stored
in a dry, cool environment
In general, companies often use several color
masterbatches to formulate specific colors for small-volume customers.
However, in the absence of the guidance of the
company's technical staff, the customer can not make their own decision to use several
color masterbatch together, and can not mix the color masterbatch produced by
different companies, in order to avoid loss caused by incompatibility.
Some pigments have an effect on the flame
retardant effect of the product. When used in flame retardant products, pls
inform the masterbatch manufacturer of this.
In order to fully display the coloring effect of the masterbatch, the mold must have a corresponding quality, especially the surface must be very smooth.
1. Heat resistance
PVC, PE pigment temperature resistance 160-180
degrees Celsius
ABS, PS pigment temperature resistance 250-280
degrees Celsius
PP, PA, PET pigments are more than 280 degrees
above temperature
It is generally required that the heat resistance
time of the pigment is 4 to 10 minutes. Generally, the higher the use
temperature, the shorter the heat resistance time. Indigo blue pigment
temperature 325 degrees Celsius, 10 minutes discoloration
2, mobility
The migration resistance of pigments means: When colored
plastic products contact with other solid, liquid, gas and other materials or
work in a specific environment for long time, may have physical and chemical
effects with the above substances, expressed as pigments from plastic interior
migrating to the free surface of the article or migrating to an adjacent
plastic or solvent.
Migration resistance rating standard
Level 1 Level 2 Level 3 Level 4 Level 5
Severe migration, significant migration,
migration, slight migration, no migration
3. Most of the inorganic pigments have good light
resistance.
4. Weather resistance refers to the color
stability of pigments under natural conditions.
5. Titanium dioxide is divided into: anatase (A)
titanium dioxide rutile (R) titanium dioxide
Titanium dioxide can improve hiding power,
tolerance, fading resistance, etc.~~~
When the concentration of titanium dioxide is low,
the whiteness of PP increases with the increase of its content. When the
concentration exceeds 1.5%, the whiteness no longer rises, from 1% to 8%, the
whiteness increases by 2.8%, which indicates that when the concentration
exceeds a certain concentration, increasing the amount of titanium dioxide does
not improve the whiteness. In order to further increase the whiteness, a fluorescent
whitening agent can be used, and the tinting strength of the titanium white
powder can be significantly improved by using only a small amount of the
fluorescent whitening agent.
Titanium dioxide
Titanium dioxide allows plastics to effectively
scatter visible light to impart whiteness, brightness, and opacity.
The concentration of titanium dioxide in PP ABS is
1%; in PVC, it is 4%; as the amount of titanium dioxide increases, the hiding
power increases gradually, and when the concentration is greater than 8%, it
tends to balance.
In general, the finer the titanium dioxide
particles, the higher the tinting strength and the stronger the hiding power.
6. Cadmium yellow has strong tinting strength,
excellent light and weather resistance, no migration, no bleed (toxic paint).
This product can be used as a yellow coloring agent for plastics. It has bright
colors, excellent light resistance, heat resistance, solvent resistance, water
resistance and alkali resistance, but it is not resistant to acid, and the
coloring and hiding power is not strong.
7. Ultramarine has the function of whitening and
coloring, which can remove the yellow color in the plastics.
Ivy Lee
Tel: (86)531 88995327
Mob/WhatsApp: (86) 18660195311
SKYPE: (86) 18660195311
WeChat: ivy897087
Email: sales1@xy-masterbatch.com
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