The six key points that determine the quality of black masterbatch
04/18/2018
First, the dispersion should be high
Black
masterbatch is produced by carbon black. Raw carbon black is mixture
that is dirty and very difficult to clean, it’s dusty, lightweight and
fluffy. Unless large-scale treatment measures are used, it will foul
machines and workers and make the working environment dirty. Because of
this, casters generally choose to finish carbon black predispersion on a
resin carrier, that is, black masterbatch. This resin carrier is clean,
free flowing and easy to use. In addition, apart from being dirty,
carbon black also has a characteristic that it is difficult to perform
dispersion. If the raw carbon black is melted directly during injection
molding, the coloring effect will be very poor. The carbon black stripes
and spots that have no dispersion will clearly show up next to the less
colored areas. Standard injection molding machines cannot disperse
carbon black effectively.
Carbon black, which is difficult to
disperse, also confuses color masterbatch producers. The high load black
masterbatch produced by single or double screw extruders has very poor
dispersibility. When the end user mixes or molds these black
masterbatches, its performance is only slightly better than carbon
black, but the effect is equally unsatisfactory. In order to achieve a
stable high degree of dispersion, a high-level shearing mixer must be
used to mix carbon black, such as a mixture of FCM or BANBURY. With
sufficient strength, these mixers can completely mix the carbon black
with the base resin. The type of carbon black used also affects the
dispersibility. The smaller the carbon black particles, the harder the
dispersion is.
The application of thin wax is in most demanding of
dispersion requirements. The final product of poorly dispersed
masterbatch can be easily seen by the naked eye from the corners. In
addition to the lack of beauty, the poor dispersion of carbon black in
the film significantly reduced the weathering resistance of the black
film. Small particles with good dispersibility are the main features of
the fiber industry. These fibers are used in ropes, yarns, carpets and
other industries. Large machines simultaneously produce 30,000 strands
of fiber at a speed of more than 5,000 meters per minute. If the
dispersion of the masterbatch is too poor, it will break the fiber and
cause production shutdown.
Second, strong coverage
The second
factor that determines the quality of black masterbatch is coverage.
This factor is especially important for masterbatches for scrap or
recycled polymers. In these cases, the role of black is to cover the
other colors in the scrap. Large-particle carbon black has poor coloring
capabilities and does not easily cover all the other underlying colors.
As a result, the final product is only deviated from the color. In the
melting process, the ability to properly select the carbon black with
high coloring ability to cover the existing color is the so-called
covering power.
Third, the liquidity is good
The third factor
that determines the quality of black masterbatch is rheology and
fluidity. If masterbatch itself has good dispersibility, but it cannot
flow into the material to be molded, the effect of the production is not
ideal. In general, the base resin used to produce the masterbatch has a
higher rheology. In order to save costs, some masterbatch manufacturers
use recycled materials, scrap as resin carriers. The flow properties of
the masterbatches being produced thus will be significantly reduced,
and if the rheology is not good, the labor will have troubles in the
cycle time and appearance. It is worth noting that if the dispersibility
and rheology are not high, some end-users will compensate by increasing
the dilution ratio, but this will only increase the using cost of
masterbatch. Color masterbatch with the smallest dilution yields a
uniform, well-dispersed black color.
Fourth, compatibility is big
The
compatibility is the fourth factor that determines the quality of the
black masterbatch. If the masterbatch is produced by swarf or recycled
material, it may contain contaminants or other non-meltable polymers.
This can cause some unforeseen and difficult constraints, wasting final
consumers' time and raw materials. At this time, the base resin can be
selected to produce high-quality masterbatch, and the masterbatch has
good compatibility in the melting process. High-quality masterbatches
can be produced by using LLDPE, LDPE, HDPE, PP, PS, SAN, PA and other
materials. If engineering grade and stringent physical properties have
been noted, special polymer masterbatches can be obtained. Several
international large-scale masterbatch manufacturers are conducting
research to produce so-called "global universal" masterbatches. These
masterbatches can be used in a wide range of other raw materials, have
good rheology, and can be applied flexibly.
Fifth, the stability should be consistent
This
is also the fifth factor that determines the quality of black
masterbatch. One of the main manifestations of stability is the smooth
carbon black ratio. If the percentage of carbon black is fluctuating,
the amount of masterbatch that needs to be melted is not the same, and
it is impossible to produce a product with the same hue. Some end-users
have reported that the dilution ratios required by chemical
manufacturers are usually 5-8% different, depending on how much material
the masterbatch manufacturer has put into production. Obviously this is
unacceptable. Of course, other factors such as the fluidity and
dispersibility of the injected melt should be consistent with the amount
of feed to each batch.
Sixth, the shade must be clear
The final
factor that determines the quality of the black masterbatch is the shade
of the color. There are various types of carbon black available on the
market for the coloring of masterbatches, but the colors and prices of
various types are also quite different. Large particle carbon black has a
lower degree of coloration and different background color than small
particle carbon black. Large-particle masterbatches are suitable for the
production of bags such as garbage bags, but are not suitable for the
production of aesthetically pleasing products such as TV signs or areas
where UV protection is required, such as agricultural films or external
pipes. For these products, only the higher-priced, small-particle carbon
blacks are used. In addition, low transparency is also a characteristic
of small particle carbon black.